![]() ![]() Giving Emma her space proves exceedingly difficult for Luke, who, in the episodes that follow, repeatedly makes decisions that prioritize her well-being over the mission objective that he surely wouldn’t were she not so dear to him.Īt first, the scenes shared by Schwarzenegger and Barbaro (“Top Gun: Maverick”) are one of the stronger suits of “FUBAR,” but they occur so regularly and are so repetitive that they wear very thin. (Emma is pretty mad at her father for making the exact life choice she made decades later.) Gabriel Luna, left, and Arnold Schwarzenegger appear in a scene from 'FUBAR." (Courtesy of Netflix) And thus begins the backbone of the series: constant arguments between Luke and Emma about secrets and trustworthiness and the need for him to stay out of her personal life. When Luke reappears in Boro’s life, he discovers the undercover agent is - you guessed it - Emma, neither knowing the other worked for the CIA. Packed with character-driven moments, ‘The Last of Us’ is a gripping adaptation of acclaimed video game | TV review Now Boro is applying all he’s learned into a plan that could lead to many deaths. Luke is quire familiar with this bad guy, Boro (Gabriel Luna, “The Last of Us”) after posing as an associate of Boro’s father, Luke killed the man, unbeknown to Boro, and worked to remain a positive influence in the young man’s life, going so far as to pay for his schooling. Retirement has to wait, though, as Luke is recruited to extract another agent from an undercover operation. We meet Luke on what is supposed to be his final mission before retiring from the CIA in the Santora-penned first episode, “Take Your Daughter to Work Day.” Things get a little hairy, but, with the help of his remote-working right-hand man, the entirely nerdy Barry (Milan Carter, “Warped!”), Luke is able to take out the bad guys. He still craves daddy-daughter time, and he doesn’t approve of her choice in partners, the kind-but-wussy Carter (Jay Baruchel of “This Is The End”). The Ni–MMT nanocomposite exhibited decent catalytic performance and recyclability of up to 6 cycles.Whereas in “True Lies” - which, by the way, recently was adapted into what proved to be a short-lived series on CBS - the story largely concerned the secrets between a husband and his wife, “FUBAR” primarily is interested in Luke’s relationship with his beloved daughter, Emma (Monica Barbaro). This nanocomposite catalyst was also applied for a process involving substituted anilines with levulinic acid, while yielding their corresponding pyrrolidone products in excellent yields. ![]() The sequential one-pot pathway was further tested on aryl and selected aliphatic aldehyde substrates with moderate to substantial yields (63–86%) for N-substituted pyrrolidones. It was observed that the sequential one-pot pathway provided significantly higher yields for the desired product with great atom economy, in comparison to the cascade pathway. This process has been catalyzed using the non-noble metal catalyst, Ni–montmorillonite (Ni–MMT) nanocomposite, which has been extensively characterized for this work. This work aims to explore cascade and sequential one-pot synthesis pathways for N-substituted pyrrolidones from aryl aldehydes and bio-derived levulinic acid (LA) using molecular hydrogen and ammonia. ![]()
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